Showing posts with label Types of quantum mechanical postulates. Show all posts
Showing posts with label Types of quantum mechanical postulates. Show all posts

QUANTUM MECHANICAL POSTULATES

The formulation of wave mechanics or quantum mechanics, by wave mechanical treatment of the, structure of the atom and rest upon a few postulates which, for a system moving in one - dimensional, and it's say, the x- coordinates are given below.

FIRST POSTULATE :
                                     The physical states of a system at time ' t' is described by the wavefunction,
                 ψ ( x, t)

SECOND POSTULATE :
                                           The wave function ψ ( x, t) and it's first and second derivatives is,

∂ψ (x,t ) / dx and d² ψ ( x, t) / ∂x²  are continuous, finite and single - valued for all values of x also, the wave function ψ ( x, t) is normalized.
That is,
    .......... (1) 

Where ψᵅ is the complex conjugate of ψ formed by replacing i with − i, wherever it's occurs in the function ψ.
               [ i = √−1 ]

THIRD POSTULATE :
                                    The physically observable quantity can be represented by a Hermitian operator.
                                 An operator A is to be Hermitian if its satisfies the following conditions. 

∫  ψᵢ*  Â ψⱼ dx = ∫ ψⱼ ( Â ψᵢ )* dx .......(2)

Where ψᵢ and ψⱼ are the wave functions and representing the physical states of the quantum system,
i.e, a particle, an atom or molecule.

FOURTH POSTULATE :

                                    The allowed values of an observable A are the eigen values, a i, in the operator equation

 ψᵢ = aᵢ ψᵢ......................... (3)
Equation (3) is known as eigenvalue equation.
Here, 
 - is the operator for the observable physical quantity
ψᵢ is an eigenfunction of  Â with eigen value aᵢ.
In other words,
Measurement of the observable A yields the eigen value aᵢ.

FIFTH POSTULATE :
                                  
                                The average value, < A> , of an observable A, is obtained from the relation
............ (4)
Where, the function ψ is assumed to be normalized in accordance with equation (1)
Thus, the average value of, it say, the x- coordinate is given by
................. (5)

SIXTH POSTULATE :

                                    The quantum mechanical operators corresponding to the observable are constructed by writing the classical expression in terms of the variables and converting the expressions to the operators. 

SEVENTH POSTULATE :

                                         The wave function ψ (x, t) is a solution of the time dependent equation. 

Ĥ ψ (psi) (x, t) = i ħ        ∂ψ ( x, t )
                                    ∂t

Where, 
                      Ĥ is the Hamiltonian operator for this system.